The Linux Host sees LUNs on the storage system as SCSI devices. When you have multiple LUNs, you must be able to persistently identify each LUN across system reboots. This means you should make sure each LUN has a unique file system label and then mount the file system using that label.
When you use multipathing, DM-Multipath automatically creates persistent devices for each LUN in the /dev/mapper/ directory on the Linux host.